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The facility serves as the principal home for several staff
members with additional research activities that are supported
by other funds.
John Hayes (retired
director of NOSAMS), maintains a program of research in isotopic
biogeochemistry. Since 1998, it has resulted in many peer-reviewed
publications which are listed in the bibliography below. Topics
include studies of carbon- and hydrogen-isotopic fractionations
imposed by phytoplankton and other microorganisms, paleoenvironmental
studies based on sedimentary isotopic and organic-geochemical
records, studies of the anaerobic oxidation of methane in
marine sediments, the long-term record of 13C in
sedimentary organic carbon, and developments in stable-isotopic
analytical techniques. On-going research supported by non-NOSAMS
funds includes many of those topics as well as studies of
14C as an inverse tracer for fossil-fuel-derived
organic materials in modern environments (with T. Eglinton
and C. Reddy) and studies of the transport and sedimentation
of biomarkers of paleoclimatic interest (with T. Eglinton
and J. McManus).
Richard Healy,
an information systems associate and manager of the NOSAMS
computer network and web site, collaborates with the NASA/Goddard
Institute for Space Studies (GISS) climate-modeling group
in New York. One aspect of the research is modeling for the
Analysis of Recent and Rapid Climate Change (ARRCC) program.
Working with the GISS general circulation model, the observed
sunspot activity during the past 500 years has been used to
estimate changes in solar irradiance and their correlation
with changes in global surface air temperature (Robertson
et al., 2001)
Ann McNichol,
the staff chemist and director of the sample-preparation laboratory,
is studying the distribution of 13C in oceanic
DIC in order to understand the ocean’s role in the uptake
of fossil-fuel-derived CO2 and to examine other
processes in the carbon cycle. Her work follows earlier examinations
of the fate of anthropogenic CO2 in the oceans
(Quay et al., 1992; Heimann and Maier-Reimer, 1996; Tans et
al., 1993) and updates them through use of the extensive data
set of δ13C values collected during the analyses
of the WOCE samples at NOSAMS.
Mark Roberts,
staff physicist is working on an initiative to re-determine
the 14C half-life. This initiative was developed in response
to questions raised by various researchers at Lamont-Doherty
Earth Observatory (Broecker, 2005; Fairbanks, 2005; Chiu,
2007), who pointed to uncertainties about the validity of
the 'accepted' 14C half-life. These groups suggested that
the currently accepted half-life of 5700 ± 30 years
might be too low. A significant shift in the 14C half-life
would impact our understanding of the 14
C calibration curve.
Preliminary results, in which the 14C half-life is determined
from knowledge of both the specific-activity and 14C/12C ratio
of the 14C counting standard OX-I, indicate that the currently
accepted half-life might actually be 1-2% too high. A paper
summarizing the work has been recently accepted for publication
in Radiocarbon.
References
Broecker W and Barker S, (2005) ‘A 190 per mil drop
in atmosphere’s Δ14C during the “Mystery
Interval” (17.5 to 14.5 kyrs)?’, submitted to
Quaternary Science Reviews.
Fairbanks RG, Mortlock RA, Chiu T-C, Cao L, Kaplana A,
Guilderson TP, Fairbanks TW, Bloom AL, Grootes PM, and Nadeau
M-J, (2005) ‘Radiocarbon calibration curve spanning
0 to 50,000 years BP based on paired 230Th/234
U/238
U and
14C dates on pristine corals, Quaternary Science Reviews
24, 1781–1796.
Chiu T-C, Fairbanks RG, Cao L, and Mortlock RA, (2007)
‘Analysis of the atmospheric 14C record spanning the
past 50,000 years derived from high-precisions 230Th/244U/238U,
231Pa/235U and 14C dates on fossil corals’, Quaternary
Science Reviews 26, 18-36
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